Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
Palaeoproterozoic crustal accretion and collision in the southern Capricorn Orogen: the Glenburgh Orogeny
2004
Abstract The Capricorn Orogen in central Western Australia records the Palaeoproterozoic collision of the Archaean Pilbara and Yilgarn Cratons. Until recently only one orogenic event was thought to be the cause of this collision, the 1830–1780 Ma Capricorn Orogeny. However, recent work has uncovered an older event, the Glenburgh Orogeny that occurred between 2000 and 1960 Ma. The Glenburgh Orogeny reflects the collision of a late Archaean to Palaeoproterozoic microcontinent (the Glenburgh Terrane) with the Archaean Yilgarn Craton and is therefore tectonically distinct as well as significantly older than the widespread 1900–1800 Ma tectonothermal events recorded in northern Australia. The Gl…
New geochemical and combined zircon U–Pb and Lu–Hf isotopic data of orthogneisses in the northern Altyn Tagh, northern margin of the Tibetan plateau:…
2014
Abstract Dunhuang Block is previously considered to be an eastern part of the Tarim Craton, but now it is proposed to be the western extension of the Alxa Block of the NCC as a result of displacement along the Altyn Tagh fault. The oldest basement rocks of the Dunhuang Block, named Aketashitage Complex, were mainly exposed in the northern Altyn Tagh. Migmatites of the Aketashitage Complex are sodic and subalkaline in composition. Zircon U–Pb dating of the tonalitic and monzogranitic migmatites indicates that these rocks were produced by strong deformation of earlier formed tonalites with innumerous granitic veins. The tonalitic melanosome of the migmatites was generated approximately at 2.7…
Zircon REE patterns and geochemical characteristics of Paleoproterozoic anatectic granite in the northern Tarim Craton, NW China: Implications for th…
2012
Abstract Because Archean basement rocks are sparsely distributed around the Tarim Basin, little is known of the relationship between the Tarim Craton and the Paleo- to Mesoproterozoic Columbia supercontinent. Zircon U–Pb dating of a Paleoproterozoic gneissic granite in the northern Tarim Craton yielded a crystallization age of 1915 ± 13 Ma, consistent with global Paleoproterozoic collisional events (ca. 2.1–1.8 Ga) recorded in most cratons. Despite the fact that some zircons display discordant U–Pb ages with a distinct loss of radiogenetic Pb, all grains have similar 176Lu/177Hf and 176Hf/177Hf(t) values. Zircons from this granite have high Th/U ratios (0.15–0.95), but contrasting rare eart…
Relationships between diffuse CO 2 emissions and volcanic activity on the island of Vulcano (Aeolian Islands, Italy) during the period 1984-1994
2002
Measurements of CO2 flux from the ground were periodically carried out on the island of Vulcano (Aeolian Islands, Italy) between 1984 and 1994. Three high-flux areas were identified at the foot of the volcanic cone (La Fossa), either inside or very close to the main village. Effect of the choice of the sampling grid was evaluated. A different sampling grid resulted in similar distribution patterns, but with different CO2 fluxes. Therefore, the absolute estimate of the total flux from the investigated area includes a large degree of uncertainty, but repeated measurements with permanent sampling sites are accurate and can detect small changes. No correlation of the flux with atmospheric param…
Isotope composition of rain water, well water and fumarole steam on the island of Vulcano, and their implications for volcanic surveillance
1992
Abstract Water samples from eight wells in the Vulcano Porto area and fumarole steam from the crater of Vulcano (Southern Italy) were collected at monthly intervals over a two-year period from February 1987 to January 1989. Samples of bulk precipitation were also collected in three points at Vulcano Porto and Vulcano Piano (island of Vulcano) and Castroreale (Tyrrhenian coast of Sicily), again at monthly intervals. The weighted mean isotopic composition of rain water on Vulcano is δ D =−32‰ , and δ D 18 O =−6.4‰ . Results for well waters tend to support the existence of at least two water bodies: one of purely meteoric water and the other of brackish thermal water. An intermediate water bod…
Plume composition and volatile flux of Nyamulagira volcano, Democratic Republic of Congo, during birth and evolution of the lava lake, 2014-2015
2017
Very little is known about the volatile element makeup of the gaseous emissions of Nyamulagira volcano. This paper tries to fill this gap by reporting the first gas composition measurements of Nyamulagira’s volcanic plume since the onset of its lava lake activity at the end of 2014. Two field surveys were carried out on 1 November 2014, and 13–15 October 2015. We applied a broad toolbox of volcanic gas composition measurement techniques in order to geochemically characterize Nyamulagira’s plume. Nyamulagira is a significant emitter of SO2, and our measurements confirm this, as we recorded SO2 emissions of up to ~ 14 kt/d during the studied period. In contrast to neighbouring Nyiragongo volc…
Emission of bromine and iodine from Mount Etna volcano
2005
[1] Constraining fluxes of volcanic bromine and iodine to the atmosphere is important given the significant role these species play in ozone depletion. However, very few such measurements have been made hitherto, such that global volcanic fluxes are poorly constrained. Here we extend the data set of volcanic Br and I degassing by reporting the first measurements of bromine and iodine emissions from Mount Etna. These data were obtained using filter packs and contemporaneous ultraviolet spectroscopic SO2 flux measurements, resulting in time-averaged emission rates of 0.7 kt yr−1 and 0.01 kt yr−1 for Br and I, respectively, from April to October 2004, from which we estimate global Br and I flu…
BrO formation in volcanic plumes
2006
Volcanoes have only recently been recognized as a potentially major source of reactive bromine species to the atmosphere, following from the detection of bromine monoxide (BrO) in the plume emitted by Soufriere Hills Volcano, Montserrat. However, BrO is not expected to be emitted in significant quantity from magma, presenting a puzzle regarding its formation. We report here new field measurements of the tropospheric plume emitted by Mt. Etna, Italy, which provide the first direct evidence of fast oxidation of halogen species in a volcanic plume, and lead to an explanation of how BrO is generated from magmatic HBr emissions. We show that the timescale of BrO formation (a few minutes after em…
Phase equilibria modelling of retrograde amphibole and clinozoisite in mafic eclogite from the Tso Morari massif, northwest India: constraining the P…
2014
Phase equilibria modelling of post-peak metamorphic mineral assemblages in (ultra)high-P mafic eclogite from the Tso Morari massif, Ladakh Himalaya, northwest India, has provided new insights into the potential behaviour and source of metamorphic fluid during exhumation, and constrained the P–T conditions of hydration. A series of P–M(H2O) pseudosections constructed in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O (NCKFMASHTO) system show that a number of petrographically distinct hydration episodes occurred during exhumation from peak P–T conditions (~640 °C, 27–28 kbar), resulting in the formation of abundant compositionally zoned amphibole and minor clinozoisite poikiloblasts at the exp…
Cognate xenoliths in Mt. Etna lavas: witnesses of the high-velocity body beneath the volcano
2013
Various xenoliths have been found in lavas of the 1763 (“La Montagnola”), 2001, and 2002–03 eruptions at Mt. Etna whose petrographic evidence and mineral chemistry exclude a mantle origin and clearly point to a cognate nature. Consequently, cognate xenoliths might represent a proxy to infer the nature of the high-velocity body (HVB) imaged beneath the volcano by seismic tomography. Petrography allows us to group the cognate xenoliths as follows: i) gabbros with amphibole and amphibole-bearing mela-gabbros, ii) olivine-bearing leuco-gabbros, iii) leuco-gabbros with amphibole, and iv) Plg-rich leuco gabbros. Geobarometry estimates the crystallization pressure of the cognate xenoliths between …